Sodium Azide → 1-(2-Azidoethoxy)-2-(2-methoxyethoxy)ethane
Reaktionsgleichung
[N-:1]=[N+:2]=[N-:3].[Na+].CS(O[CH2:10][CH2:11][O:12][CH2:13][CH2:14][O:15][CH2:16][CH2:17][O:18][CH3:19])(=O)=O>>[N:1]([CH2:10][CH2:11][O:12][CH2:13][CH2:14][O:15][CH2:16][CH2:17][O:18][CH3:19])=[N+:2]=[N-:3]Komponenten
3
Reaktionsbedingungen
- Temperatur
- 60 °C
Versuchsvorschrift
Sodium azide (5.37 g, 83 mmol) and 2-(2-(2-methoxyethoxy)ethoxy)ethyl methanesulfonate (20 g, 83 mmol) were added without solvent, the temperature was raised to 60° C. and the mixture stirred for 48 hours. The salts were filtered and ethyl acetate added to precipitate the dissolved salts and filtered again, producing 1-azido-2-(2-(2-methoxyethoxy)ethoxy)ethane.
Aufarbeitung
- filtrationThe salts were filtered
- additionethyl acetate added
- customto precipitate the dissolved salts
- filtrationfiltered again
Quellen und Nachweise
- ORD-Eintrag
- ord-1d68b5e84bf64c40a540fae73b89155e
- Quelldatensatz
- uspto-grants-2014_12
- Patentnummer
- US08906135B1
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