Methyl iodide → HCID 178439609, Verbindung

HRID 1399403Notizen

Reaktionsgleichung

Reaktionsgleichung von HRID 1399403
[CH2:1]([C:4]1[N:5]=[N:6][N:7]([CH2:9][Si:10]([CH3:13])([CH3:12])[CH3:11])[CH:8]=1)[CH2:2][CH3:3].[I:14][CH3:15]>C(#N)C>[I-:14].[CH3:15][N+:5]1[C:4]([CH2:1][CH2:2][CH3:3])=[CH:8][N:7]([CH2:9][Si:10]([CH3:13])([CH3:12])[CH3:11])[N:6]=1

Komponenten

4

Edukt 2

HCID 6328Methyl iodideHCID 131732124HCID 131732124, Verbindung

Produkt 1

HCID 178439609HCID 178439609, Verbindung

Reagenzien, Katalysatoren, Lösungsmittel 1

HCID 6342AcetonitrileLösungsmittel

Versuchsvorschrift

4-propyl-1-((trimethylsilyl)methyl)-1H-1,2,3-triazole and excess iodomethane were added to a vial and heated for about 19 and 5 mL ACN was added. The reaction was heated for another 2 hours. The precipitate was filtered, rinsed with ether and dried in vacuo overnight. The following 3-methyl-4-propyl-1-((trimethylsilyl)methyl)-1H-1,2,3-triazol-3-ium iodide structure was confirmed:

Aufarbeitung

  1. additionwas added
  2. temperatureThe reaction was heated for another 2 hours
  3. filtrationThe precipitate was filtered
  4. washrinsed with ether
  5. customdried in vacuo overnight

Quellen und Nachweise

ORD-Eintrag
ord-cc5166db45ee4999b0aeb2f941762d4d
Quelldatensatz
uspto-grants-2014_12
Patentnummer
US08906135B1

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