Benzyl Bromide → 6-Benzyloxy-1,2,3,4-tetrahydro-naphthalene-2-carboxylic Acid

HRID 1411

Reaktionsgleichung

[OH:1][C:2]1[CH:3]=[C:4]2[C:9](=[CH:10][CH:11]=1)[CH2:8][CH:7]([C:12]([OH:14])=[O:13])[CH2:6][CH2:5]2.[CH2:15](Br)[C:16]1[CH:21]=[CH:20][CH:19]=[CH:18][CH:17]=1.[OH-].[K+]>>[CH2:15]([O:1][C:2]1[CH:3]=[C:4]2[C:9](=[CH:10][CH:11]=1)[CH2:8][CH:7]([C:12]([OH:14])=[O:13])[CH2:6][CH2:5]2)[C:16]1[CH:21]=[CH:20][CH:19]=[CH:18][CH:17]=1

Komponenten

Edukt 3

HCID 7498Benzyl Bromide

HCID 14797Potassium Hydroxide

HCID 190700016-Hydroxy-1,2,3,4-tetrahydronaphthalene-2-carboxylic acid

Produkt 1

HCID 190699736-Benzyloxy-1,2,3,4-tetrahydro-naphthalene-2-carboxylic Acid

Versuchsvorschrift

The 1,2,3,4-tetrahydro-6-hydroxynaphthalene-2-carboxylic acid obtained in the above manner is reacted with benzyl bromide in the presence of potassium hydroxide to obtain 1,2,3,4-tetrahydro-6-benzyloxynaphthalene-2-carboxylic acid (11).

Quellen und Nachweise

ORD-Eintrag: ord-eac9be152119468d80a973981c8b50e8
Quelldatensatz: uspto-grants-1998_03
DOI: 10.6084/m9.figshare.5104873.v1
Patentnummer: US05725798

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