(6aR,7S,9aS,13aS)-5-benzyloxy-2,3,6,6a,7,8,9,9a,10,11,12,13-dodecahydro-6a,7,10,10-tetramethyl-11-(1-oxa-4-azacyclohex-4-yl)imino-3-oxo-1H-benzo[8,8a][1]benzopyrano[2,3-e]isoindole → (6aR,7S,9aS,13aS)-2,3,6,6a,7,8,9,9a,10,11,12,13-dodecahydro-5-hydroxy-6a,7,10,10-tetramethyl-11-(1-oxa-4-azacyclohex-4-yl)imino-3-oxo-1H-benzo[8,8a][1]benzopyrano[2,3-e]isoindole
Reaktionsgleichung
C([O:8][C:9]1[C:10]2[CH2:22][C@:21]3([CH3:41])[C@@H:23]([CH3:40])[CH2:24][CH2:25][C@H:26]4[C:27]([CH3:39])([CH3:38])[C:28](=[N:31][N:32]5[CH2:37][CH2:36][O:35][CH2:34][CH2:33]5)[CH2:29][CH2:30][C@@:20]34[O:19][C:11]=2[C:12]2[CH2:13][NH:14][C:15](=[O:18])[C:16]=2[CH:17]=1)C1C=CC=CC=1>CO.[C].[Pd]>[OH:8][C:9]1[C:10]2[CH2:22][C@:21]3([CH3:41])[C@@H:23]([CH3:40])[CH2:24][CH2:25][C@H:26]4[C:27]([CH3:39])([CH3:38])[C:28](=[N:31][N:32]5[CH2:33][CH2:34][O:35][CH2:36][CH2:37]5)[CH2:29][CH2:30][C@@:20]34[O:19][C:11]=2[C:12]2[CH2:13][NH:14][C:15](=[O:18])[C:16]=2[CH:17]=1Komponenten
4
