(9Z,12R,15Z)-12-hydroxyoctadeca-9,15-dienoic acid → Ricinoleic Acid

HRID 1424696

Reaktionsgleichung

Reaktionsgleichung von HRID 1424696
[CH3:1][CH2:2]/[CH:3]=[CH:4]\[CH2:5][CH2:6][C@@H:7]([OH:21])[CH2:8]/[CH:9]=[CH:10]\[CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][C:18]([OH:20])=[O:19].[CH3:22][CH2:23]/[CH:24]=[CH:25]\[CH2:26][CH2:27][CH:28]([OH:44])[CH2:29]/[CH:30]=[CH:31]\[CH2:32][CH2:33][CH2:34][CH2:35][CH2:36][CH2:37][CH2:38][CH2:39][CH2:40][C:41]([OH:43])=[O:42]>>[C:18]([OH:20])(=[O:19])[CH2:17][CH2:16][CH2:15][CH2:14][CH2:13][CH2:12][CH2:11]/[CH:10]=[CH:9]\[CH2:8][C@@H:7]([CH2:6][CH2:5][CH2:4][CH2:3][CH2:2][CH3:1])[OH:21].[CH3:22][CH2:23][CH2:24][CH2:25][CH2:26][CH2:27][C@@H:28]([OH:44])[CH2:29]/[CH:30]=[CH:31]\[CH2:32][CH2:33][CH2:34][CH2:35][CH2:36][CH2:37][CH2:38][CH2:39][CH2:40][C:41]([OH:43])=[O:42]

Komponenten

4

Edukt 2

HCID 5312831(9Z,12R,15Z)-12-hydroxyoctadeca-9,15-dienoic acidHCID 73242169Auricolic acid

Produkt 2

HCID 643684Ricinoleic AcidHCID 5312810Lesquerolic acid

Versuchsvorschrift

The process is particularly advantageous for feedstocks comprising densipolic acid and auricolic acid, as or not as a mixture with ricinoleic acid and lesquerolic acid, as, after hydrogenation, saturated acids having the same C18 or C20 chain length are obtained.

Quellen und Nachweise

ORD-Eintrag
ord-4d3346640814456687bdcb34cbbbc9b3
Quelldatensatz
uspto-grants-2015_01
Patentnummer
US08927746B2

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