Manganese → gamma-Cyclodextrin Manganese

HRID 1428696

Reaktionsgleichung

Reaktionsgleichung von HRID 1428696
[Mn:1].[CH2:2]([OH:88])[C@H:3]1[O:8][C@@H:7]2[O:9][C@H:10]3[C@H:15]([OH:16])[C@@H:14]([OH:17])[C@@H:13]([O:18][C@H:19]4[C@H:24]([OH:25])[C@@H:23]([OH:26])[C@@H:22]([O:27][C@H:28]5[C@H:33]([OH:34])[C@@H:32]([OH:35])[CH:31]([O:36][CH:37]6[C@H:42]([OH:43])[C@@H:41]([OH:44])[CH:40]([CH:45]7[C@H:50]([OH:51])[C@@H:49]([OH:52])[CH:48]([O:53][C@H:54]8[C@H:59]([OH:60])[C@@H:58]([OH:61])[C@@H:57]([O:62][C@H:63]9[C@H:69]([OH:70])[C@@H:68]([OH:71])[C@@H:66]([O:67][C@H:4]1[C@H:5]([OH:87])[C@H:6]2[OH:86])[O:65][C@@H:64]9[CH2:72][OH:73])[O:56][C@@H:55]8[CH2:74][OH:75])[O:47][C@@H:46]7[CH2:76][OH:77])[O:39][C@@H:38]6[CH2:78][OH:79])[O:30][C@@H:29]5[CH2:80][OH:81])[O:21][C@@H:20]4[CH2:82][OH:83])[O:12][C@@H:11]3[CH2:84][OH:85]>>[CH2:2]([OH:88])[C@H:3]1[O:8][C@@H:7]2[O:9][C@H:10]3[C@H:15]([OH:16])[C@@H:14]([OH:17])[C@@H:13]([O:18][C@H:19]4[C@H:24]([OH:25])[C@@H:23]([OH:26])[C@@H:22]([O:27][C@H:28]5[C@H:33]([OH:34])[C@@H:32]([OH:35])[CH:31]([O:36][CH:37]6[C@H:42]([OH:43])[C@@H:41]([OH:44])[CH:40]([CH:45]7[C@H:50]([OH:51])[C@@H:49]([OH:52])[CH:48]([O:53][C@H:54]8[C@H:59]([OH:60])[C@@H:58]([OH:61])[C@@H:57]([O:62][C@H:63]9[C@H:69]([OH:70])[C@@H:68]([OH:71])[C@@H:66]([O:67][C@H:4]1[C@H:5]([OH:87])[C@H:6]2[OH:86])[O:65][C@@H:64]9[CH2:72][OH:73])[O:56][C@@H:55]8[CH2:74][OH:75])[O:47][C@@H:46]7[CH2:76][OH:77])[O:39][C@@H:38]6[CH2:78][OH:79])[O:30][C@@H:29]5[CH2:80][OH:81])[O:21][C@@H:20]4[CH2:82][OH:83])[O:12][C@@H:11]3[CH2:84][OH:85].[Mn:1]

Komponenten

3

Edukt 2

HCID 23930Manganese2×HCID 44431027gamma-Cyclodextrine

Produkt 1

HCID 131732361gamma-Cyclodextrin Manganese

Versuchsvorschrift

23 g of a manganese-based drier, Manganese CEM-ALL® 12% solution (OM Group, Inc.) was added to the above-noted γ-cylodextrin solution. A brown precipitate formed upon addition of the drier. The mixture was stirred for at least 16 hours. The precipitate was filtered off under reduced pressure. The filtrate was light yellow coloured. The precipitate was dried under reduced pressure (around 19 InHg) at 50-60° C. The FTIR spectrum of the resultant inclusion complex is provided in FIG. 1(d).

Aufarbeitung

  1. customA brown precipitate formed upon addition of the drier
  2. filtrationThe precipitate was filtered off under reduced pressure
  3. dry with materialThe precipitate was dried under reduced pressure (around 19 InHg) at 50-60° C
  4. customThe FTIR spectrum of the resultant inclusion complex is provided in FIG. 1(d)

Quellen und Nachweise

ORD-Eintrag
ord-be88e115df0e4cc88356a4c07548ff8c
Quelldatensatz
uspto-grants-2015_01
Patentnummer
US08937119B2

Verknüpfte Notizen

Wird geladen…