Acetate → ethyl 5-methoxy-1a,2,3,7b-tetrahydro-1H-cyclopropa[a]naphthalene-1-carboxylate

Reaktionsgleichung

[C:21]([O-:22])(=[O:23])[CH3:24].[C:26]([O-:27])(=[O:28])[CH3:29].[C:30]([O-:31])(=[O:32])[CH3:33].[CH2:34]([Cl:35])[Cl:36].[CH3:1][O:2][c:3]1[cH:4][cH:5][c:6]2[c:11]([cH:12]1)[CH2:10][CH2:9][CH:8]=[CH:7]2.[N+:13](=[N-:14])=[CH:15][C:16](=[O:17])[O:18][CH2:19][CH3:20].[Rh+3:25]>>[CH3:1][O:2][c:3]1[cH:4][cH:5][c:6]2[c:11]([cH:12]1)[CH2:10][CH2:9][CH:8]1[CH:7]2[CH:15]1[C:16](=[O:17])[O:18][CH2:19][CH3:20]

Komponenten

Edukt 5

HCID 175Acetate3×

HCID 6344Dichloromethane

HCID 12192Ethyl diazoacetate

HCID 167511Rhodium(3+)

HCID 5947787-Methoxy-1,2-dihydronaphthalene

Produkt 1

HCID 23001093ethyl 5-methoxy-1a,2,3,7b-tetrahydro-1H-cyclopropa[a]naphthalene-1-carboxylate

Quellen und Nachweise

ORD-Eintrag: ord-5873c06c13fd413c8e28c709b23a3401
Quelldatensatz: Training data from https://doi.org/10.1039/C8SC04228D (9/10)
DOI: 10.1039/C8SC04228D

Notizen zur Reaktion

Wird geladen…