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HuagongsheHuagongshe Chemie-Druckbericht · Nur für Forschungszwecke
HRID 1433868Erstellt: 26. Oktober 2026

4-Bromo-3-nitrobenzotrifluoride → 7-Methoxy-3-(2-nitro-4-trifluoromethylphenyl)-1,2-dihydronaphthalene

https://huagongshe.com/reaction/1433868

Reaktionsgleichung

Beteiligte Stoffe

RolleNameHCIDEinwaage
Edukt4-Bromo-3-nitrobenzotrifluorideHCID 520706—
Edukt6-Methoxy-3,4-dihydronaphthalen-2-yl trifluoromethanesulfonateHCID 15330256—
EduktTributyl(2-nitro-4-trifluoromethylphenyl)tinHCID 23087363—
Produkt7-Methoxy-3-(2-nitro-4-trifluoromethylphenyl)-1,2-dihydronaphthaleneHCID 23087467—

Reaktionsschritte

Synthesized from 1-bromo-2-nitro-4-trifluoromethylbenzene according to an analogous synthetic method to Preparation Example 76, tributyl(2-nitro-4-trifluoromethylphenyl)tin (7.4 g) and 6-methoxy-3,4-dihydronaphthalen-2-yl trifluoromethanesulfonate (2.2 g) were used according to an analogous synthetic method to Preparation Example 77 to provide 7-methoxy-3-(2-nitro-4-trifluoromethylphenyl)-1,2-dihydronaphthalene (1.5 g). The total amount of this compound was used according to an analogous synthetic method to Example 30 to provide the title compound (1.0 g).

Herkunft & Nachweise

DOI10.6084/m9.figshare.5104873.v1
PatentnummerUS07612114B2
Quelldatensatzuspto-grants-2009_11
ORD IDord-d00daee45e914c9cbcda05ad34a62def
Quellennotizuspto-grants-2009_11