Benzyl Alcohol → Benzyl 4-carboxyphenylacetate

HRID 1434461Notizen

Reaktionsgleichung

Reaktionsgleichung von HRID 1434461
C(C1C=CC(CC(O)=O)=CC=1)=[O:2].C(O)C1C=CC=CC=1.[CH:21]([C:23]1[CH:28]=[CH:27][C:26]([CH2:29][C:30]([O:32][CH2:33][C:34]2[CH:39]=[CH:38][CH:37]=[CH:36][CH:35]=2)=[O:31])=[CH:25][CH:24]=1)=[O:22]>>[CH2:33]([O:32][C:30]([CH2:29][C:26]1[CH:25]=[CH:24][C:23]([C:21]([OH:2])=[O:22])=[CH:28][CH:27]=1)=[O:31])[C:34]1[CH:39]=[CH:38][CH:37]=[CH:36][CH:35]=1

Komponenten

4

Edukt 3

HCID 244Benzyl AlcoholHCID 113441872-(4-formylphenyl)acetic AcidHCID 19966221Benzyl 2-(4-formylphenyl)acetate

Produkt 1

HCID 19966080Benzyl 4-carboxyphenylacetateAusbeute 80,6 %

Versuchsvorschrift

Synthesized from (4-formylphenyl)acetic acid (1 g) and benzyl alcohol (730 mg) according to an analogous synthetic method to Example 806, benzyl (4-formylphenyl)acetate (1.4 g) was used according to an analogous synthetic method to Preparation Example 53 to provide the title compound (1.2 g).

Aufarbeitung

  1. customwas used according to an analogous synthetic method to Preparation Example 53

Quellen und Nachweise

ORD-Eintrag
ord-0dcf9ef6c13040879ab69e788806e3d1
Quelldatensatz
uspto-grants-2009_11
Patentnummer
US07612114B2

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