p-Toluenesulfonic acid → HCID 53642864, Verbindung

HRID 1438699Notizen

Reaktionsgleichung

Reaktionsgleichung von HRID 1438699
[CH3:1][N:2]1[C:7](=[O:8])[NH:6][CH:5]([S:9][CH3:10])[N:4]([N:11]=C(C)C)[C:3]1=[O:15].C1(C)C=CC(S(O)(=O)=O)=CC=1>C(O)C>[CH3:1][N:2]1[C:7](=[O:8])[NH:6][CH:5]([S:9][CH3:10])[N:4]([NH2:11])[C:3]1=[O:15]

Komponenten

4

Edukt 2

HCID 6101p-Toluenesulfonic acidHCID 53804495HCID 53804495, Verbindung

Produkt 1

HCID 53642864HCID 53642864, VerbindungAusbeute 96 %

Reagenzien, Katalysatoren, Lösungsmittel 1

HCID 702EthanolLösungsmittel

Versuchsvorschrift

22.8 g (0.1 mole) of 1-methyl-3-isopropylideneamino-4-methylmercapto-tetrahydro-1,3,5-triazine-2,6-dione (prepared according to Example 1) were dissolved in 250 ml of ethanol and warmed, with addition of a pinch of p-toluene-sulphonic acid, for 5 hours to 50° C, whilst applying a vacuum of about 200 mm Hg. The mixture was evaporated in vacuo and the residue was recrystallized from ethanol. 18 g (96%) of 1-methyl3-amino-4-methylmercapto-tetrahydro-1,3,5-triazine-2,6-dione were obtained as colorless needles; melting point 174°-175° C.

Aufarbeitung

  1. customThe mixture was evaporated in vacuo
  2. customthe residue was recrystallized from ethanol

Quellen und Nachweise

ORD-Eintrag
ord-9d499fb7000b4a3bbae9377699672e6d
Quelldatensatz
uspto-grants-1977_11
Patentnummer
US04056527

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