Cyclohexanone, 2-propyl- → Methyl 3-(1-methyl-2-oxocyclohexyl)propanoate

HRID 1438917

Reaktionsgleichung

CC1CCCCC1=O.C(C1CCCCC1=O)C.C(C1CCCCC1=O)CC.[CH3:28][O:29][C:30](=[O:42])[CH2:31][CH2:32][C:33]1([CH2:40]C)[CH2:38][CH2:37][CH2:36][CH2:35][C:34]1=[O:39].COC(=O)CCC1(CCC)CCCCC1=O>>[CH3:28][O:29][C:30](=[O:42])[CH2:31][CH2:32][C:33]1([CH3:40])[CH2:38][CH2:37][CH2:36][CH2:35][C:34]1=[O:39]

Komponenten

Edukt 5

HCID 7199Cyclohexanone, 2-propyl-

HCID 114192-Methylcyclohexanone

HCID 204742-Ethylcyclohexanone

HCID 122918881-Ethyl-2-oxocyclohexanepropionic acid methyl ester

HCID 227572861-Propyl-2-oxocyclohexanepropionic methyl ester

Produkt 1

HCID 574325Methyl 3-(1-methyl-2-oxocyclohexyl)propanoate

Versuchsvorschrift

in the same manner but replacing 2-methylcyclohexanone with an equivalent amount of 2-ethylcyclohexanone or 2-propylcyclohexanone, 1-ethyl-2-oxocyclohexanepropionic acid methyl ester, bp 117° - 120° C/0.4mm, and 1-propyl-2-oxocyclohexanepropionic methyl ester, νmaxCHCl3 1735, 1700cm-1, are obtained, respectively.

Aufarbeitung

customνmaxCHCl3 1735, 1700cm-1, are obtained

Quellen und Nachweise

ORD-Eintrag: ord-024b0687b64941429e696cf79681d3c6
Quelldatensatz: uspto-grants-1977_11
DOI: 10.6084/m9.figshare.5104873.v1
Patentnummer: US04057559

Verknüpfte Notizen

Wird geladen…