Thiocyanic Acid → HCID 86735207, Verbindung

HRID 1439376

Reaktionsgleichung

Reaktionsgleichung von HRID 1439376
[OH:1][CH:2]([C:7]1[CH:12]=[CH:11][CH:10]=[CH:9][CH:8]=1)[CH2:3][N:4]1[CH2:6][CH2:5]1.[N:13]#[C:14][SH:15]>O1CCOCC1>[S-:15][C:14]#[N:13].[NH:13]=[C:14]1[N:4]([CH2:3][CH:2]([OH:1])[C:7]2[CH:8]=[CH:9][CH:10]=[CH:11][CH:12]=2)[CH2:6][CH2:5][S:15]1

Komponenten

4

Edukt 2

HCID 781Thiocyanic AcidHCID 288341-Aziridineethanol, .alpha.-phenyl-

Produkt 1

HCID 86735207HCID 86735207, VerbindungAusbeute 96 %

Reagenzien, Katalysatoren, Lösungsmittel 1

HCID 312751,4-DioxaneLösungsmittel

Versuchsvorschrift

A solution of 1-hydroxy-1-phenyl-2-ethyleniminoethane (16.3 g) in dioxan (35 ml) was added dropwise and with stirring at 0° C to an aqueous solution of thiocyanic acid (200 ml of 1N solution). After the addition the mixture was stirred in the cold for 1 hour. It was then heated under reflux for 1 hour and the solution cooled. The desired compound crystallised in 96% yield, m.p. 160° C.

Aufarbeitung

  1. additionAfter the addition the mixture
  2. temperatureIt was then heated
  3. temperatureunder reflux for 1 hour
  4. temperaturethe solution cooled
  5. customThe desired compound crystallised in 96% yield, m.p. 160° C.

Quellen und Nachweise

ORD-Eintrag
ord-02459d4d0d8944cc95342dd3830824a8
Quelldatensatz
uspto-grants-1977_11
Patentnummer
US04059588

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