Potassium Hydroxide → 2-Imino-1,3-dimethylimidazolidin-4-one

HRID 1440760

Reaktionsgleichung

Reaktionsgleichung von HRID 1440760
[OH-].[K+].I.[NH:4]=[C:5]1[N:9]([CH3:10])[C:8](=[O:11])[CH2:7][N:6]1[CH3:12]>CO>[NH:4]=[C:5]1[N:9]([CH3:10])[C:8](=[O:11])[CH2:7][N:6]1[CH3:12]

Komponenten

4

Edukt 2

HCID 14797Potassium HydroxideHCID 214757732-Imino-1,3-dimethylimidazolidin-4-one hydroiodide

Produkt 1

HCID 140604272-Imino-1,3-dimethylimidazolidin-4-oneAusbeute 90,3 %

Reagenzien, Katalysatoren, Lösungsmittel 1

HCID 887MethanolLösungsmittel

Versuchsvorschrift

Then, to 150 ml of a methanol solution containing 5.17 g (78.4 mmol) of 85% potassium hydroxide, 20 g (78.4 mmol) of 2-imino-1,3-dimethylimidazolidin-4-one hydroiodide was added, and the mixture was stirred at room temperature for 20 minutes. The solvent was distilled off under reduced pressure. Then, to the residue, 200 ml of chloroform was added, and insoluble matters were filtered off. The filtrate was dried over anhydrous magnesium sulfate, and the solvent was distilled off under reduced pressure to obtain 9.0 g of 2-imino-1,3-dimethylimidazolidin-4-one.

Aufarbeitung

  1. additionwas added
  2. distillationThe solvent was distilled off under reduced pressure
  3. additionThen, to the residue, 200 ml of chloroform was added
  4. filtrationinsoluble matters were filtered off
  5. dry with materialThe filtrate was dried over anhydrous magnesium sulfate
  6. distillationthe solvent was distilled off under reduced pressure

Quellen und Nachweise

ORD-Eintrag
ord-2d373fb16f214615bd4b02e155eebd77
Quelldatensatz
uspto-grants-1996_03
Patentnummer
US05500406

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