2,2'-Bipyridine → HCID 12503695, Verbindung

HRID 1447706Notizen

Reaktionsgleichung

Reaktionsgleichung von HRID 1447706
[N:1]1[CH:6]=[CH:5][CH:4]=[CH:3][C:2]=1[C:7]1[CH:12]=[CH:11][CH:10]=[CH:9][N:8]=1.[CH:13]1([CH2:19]C2C=CN=CC=2)[CH2:18][CH2:17][CH2:16][CH2:15][CH2:14]1>>[CH:13]1([CH2:19][C:4]2[CH:5]=[CH:6][N:1]=[C:2]([C:7]3[CH:12]=[C:11]([CH2:19][CH:13]4[CH2:14][CH2:15][CH2:16][CH2:17][CH2:18]4)[CH:10]=[CH:9][N:8]=3)[CH:3]=2)[CH2:18][CH2:17][CH2:16][CH2:15][CH2:14]1

Komponenten

3

Edukt 2

HCID 14742,2'-BipyridineHCID 224476584-(Cyclohexylmethyl)pyridine

Produkt 1

HCID 12503695HCID 12503695, Verbindung

Versuchsvorschrift

The mixture was then cooled to room temperature and hydrolyzed with 50 cc of water. The oil layer was separated, and the aqueous phase was extracted with 50 cc additional xylene. The oil layer and extract were combined and distilled to give 82.4 g of unreacted 4-cyclohexylmethylpyridine (0.47 mole) and 9.0 g (0.03 mole) of 4,4'-di-(cyclohexylmethyl)-2,2'-bipyridyl boiling at 273°-276° C. at 2.5 mm Hg. The yield of 2,2'-bipyridyl product was calculated at 43.3% based on the amount of 4-cyclohexylmethylpyridine consumed. This 2,2'-bipyridyl compound (recrystallized from isopropanol) gave a melting point of 117°-119° C.

Aufarbeitung

  1. customconsumed

Quellen und Nachweise

ORD-Eintrag
ord-42c822b98b2e4182b8b360098511217b
Quelldatensatz
uspto-grants-1979_12
Patentnummer
US04177349

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