1-Decanol → Magnesium decanolate

HRID 1447774Notizen

Reaktionsgleichung

Reaktionsgleichung von HRID 1447774
C([O-])(C)C.[Mg+2:5].C([O-])(C)C.[Mg].[CH2:11]([OH:21])[CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][CH3:20]>C(O[Ti](OCCCC)(OCCCC)OCCCC)CCC.C(O)(C)C>[CH2:11]([O-:21])[CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][CH3:20].[CH2:11]([O-:21])[CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][CH3:20].[Mg+2:5]

Komponenten

6

Edukt 3

HCID 81741-DecanolHCID 5462224Magnesium2×HCID 10197750Magnesium dipropan-2-olate

Produkt 1

HCID 21149434Magnesium decanolate

Reagenzien, Katalysatoren, Lösungsmittel 2

HCID 178454852HCID 178454852, VerbindungKatalysatorHCID 3776IsopropanolLösungsmittel

Versuchsvorschrift

If magnesium isopropanolate, together with e.g., 20 moles % of tetrabutoxy titanium, with respect to the amount of magnesium, and one or two equivalents of decanol, is introduced into an organic solvent, and the mixture is heated, a desirably low-viscosity solution of magnesium isopropanolatedecanolate, and/or of magnesium didecanolate, is formed, from which the liberated isopropanol can now readily be evaporated so as to achieve substantially full completion of the reaction.

Aufarbeitung

  1. temperaturethe mixture is heated

Quellen und Nachweise

ORD-Eintrag
ord-e1e9c9fb7ba042fb99b0bb40dead3839
Quelldatensatz
uspto-grants-1979_12
Patentnummer
US04178300

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