Sodium Hydroxide → (Octylcarbamoyl)formic acid
Reaktionsgleichung
[CH2:1]([NH:9][C:10](=[O:16])[C:11]([O:13]CC)=[O:12])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH3:8].[OH-].[Na+]>CO>[CH2:1]([NH:9][C:10](=[O:16])[C:11]([OH:13])=[O:12])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH3:8]Komponenten
4
Edukt 2
Produkt 1
Reagenzien, Katalysatoren, Lösungsmittel 1
Versuchsvorschrift
To a solution of ethyl N-(n-octyl)oxamate (5 g., 0.022 mole) in methanol (50 ml.) is added slowly NaOH solution (20 ml. of 1 N NaOH diluted with 25 ml. of H2O). After standing for one hour, the mixture is evaporated until the residue is mainly solid. 6 N HCl solution (75 ml.) is added. After stirring for 1 hour the solids are removed by filtration and dried. The yield of N-(n-octyl)oxamic is 3.85 g. (m.p. 89°-93° C.).
Aufarbeitung
- customthe mixture is evaporated until the residue
- addition6 N HCl solution (75 ml.) is added
- customare removed by filtration
- customdried
Quellen und Nachweise
- ORD-Eintrag
- ord-a847f8af2cf74e01a49807a16ed9a132
- Quelldatensatz
- uspto-grants-1980_02
- Patentnummer
- US04187315
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