Cyclobutanecarbonyl chloride → HCID 15289311, Verbindung
Reaktionsgleichung
[CH2:1]([CH:10]1[CH2:15][CH2:14][CH2:13][CH2:12][NH:11]1)/[CH:2]=[CH:3]/[C:4]1[CH:9]=[CH:8][CH:7]=[CH:6][CH:5]=1.[CH:16]1([C:20](Cl)=[O:21])[CH2:19][CH2:18][CH2:17]1>>[CH2:1]([CH:10]1[CH2:15][CH2:14][CH2:13][CH2:12][N:11]1[C:20]([CH:16]1[CH2:19][CH2:18][CH2:17]1)=[O:21])/[CH:2]=[CH:3]/[C:4]1[CH:9]=[CH:8][CH:7]=[CH:6][CH:5]=1.[CH2:1]([CH:10]1[CH2:15][CH2:14][CH2:13][N:11]1[C:20]([CH:16]1[CH2:19][CH2:18]1)=[O:21])/[CH:2]=[CH:3]/[C:4]1[CH:5]=[CH:6][CH:7]=[CH:8][CH:9]=1Komponenten
4
Versuchsvorschrift
Stage a) The method is the same as that of Example 1.1, Stage a), the initial reactants being (E)-2-(cinnamyl)piperidine and cyclobutanecarboxylic acid chloride, which furnish (E)-2-cinnamyl-1-(cyclobutanecarbonyl)piperidine (formula II; Ar=C6 H5, m=1, n=2, R=cyclobutyl). Yield: 99%.
Quellen und Nachweise
- ORD-Eintrag
- ord-4d1f690645f7455a9bb10ad3aa2008e8