Phenolate Sodium → HCID 53711277, Verbindung
Reaktionsgleichung
[Cl:1][C:2](Cl)=[CH:3][C:4]([CH3:7])([CH3:6])[CH3:5].[C:9]1([O-:15])[CH:14]=[CH:13][CH:12]=[CH:11][CH:10]=1.[Na+]>CN(C)C=O>[Cl:1][CH:2]=[C:3]([O:15][C:9]1[CH:14]=[CH:13][CH:12]=[CH:11][CH:10]=1)[C:4]([CH3:7])([CH3:6])[CH3:5]Komponenten
4
Edukt 2
Produkt 1
Reagenzien, Katalysatoren, Lösungsmittel 1
Versuchsvorschrift
16.5 g (0.108 mols) of 1,1-dichloro-3,3-dimethyl-1-butene are heated under reflux with 23.2 g (0.2 mol) of sodium phenolate in 100 ml of dimethylformamide, during the course of 12 hours. The customary working-up according to Example A1(a) yields, with distillation at a boiling point of 80° C./0.5 mm Hg, 22.3 g of 1-chloro-3,3-dimethyl-2-phenoxy-1-butene.
Quellen und Nachweise
- ORD-Eintrag
- ord-85deab2f33f946c5a9227753d15e8e5d
- Quelldatensatz
- uspto-grants-1984_07
- Patentnummer
- US04460793
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