Aluminum(III) Chloride → 2-Chloro-1,3,5-trimethylbenzene

HRID 1464709Notizen

Reaktionsgleichung

Reaktionsgleichung von HRID 1464709
[Cl-:1].[Al+3].[Cl-].[Cl-].ClC(O[C:9]1[C:14]([CH3:15])=[CH:13][C:12]([CH3:16])=[CH:11][C:10]=1[CH3:17])=O>>[CH3:17][C:10]1[CH:11]=[C:12]([CH3:16])[CH:13]=[C:14]([CH3:15])[C:9]=1[Cl:1]

Komponenten

3

Edukt 2

HCID 6451240Aluminum(III) ChlorideHCID 11106338HCID 11106338, Verbindung

Produkt 1

HCID 154622-Chloro-1,3,5-trimethylbenzeneAusbeute 72 %

Reaktionsbedingungen

Temperatur
180 °C

Versuchsvorschrift

0.5 g of anhydrous aluminium chloride was added to 50 g of 2,4,6-trimethylphenyl chloroformate and the mixture was heated at 180° C. for 1.5 hours at normal pressure. The reaction mixture was then cooled and worked up as described in Example 1. 2,4,6-Trimethylchlorobenzene was obtained in a yield of 72%.

Aufarbeitung

  1. temperatureThe reaction mixture was then cooled

Quellen und Nachweise

ORD-Eintrag
ord-4fbf6cec25314c99abef0b6483b7377f
Quelldatensatz
uspto-grants-1994_04
Patentnummer
US05306849

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