Triethyl phosphite → allyl (4R,5S,6S)-6-[(1R)-1-(tert-butyldimethylsilyloxy)ethyl]-4-methyl-3-methylthio-7-oxo-1-azabicyclo[3.2.0]hept-2-ene-2-carboxylate
Reaktionsgleichung
P(OCC)(OCC)OCC.[CH2:11]([O:14][C:15](=[O:39])[C:16]([N:18]1[C@H:21]([C@H:22]([C:24]([S:26][CH3:27])=S)[CH3:23])[C@@H:20]([C@H:28]([O:30][Si:31]([C:34]([CH3:37])([CH3:36])[CH3:35])([CH3:33])[CH3:32])[CH3:29])[C:19]1=[O:38])=O)[CH:12]=[CH2:13].C(OC(=O)C(N1[C@H]([C@@H](C(SC)=S)C)[C@@H]([C@H](O[Si](C(C)(C)C)(C)C)C)C1=O)=O)C=C>C1(C)C=CC=CC=1>[Si:31]([O:30][C@@H:28]([C@H:20]1[C:19](=[O:38])[N:18]2[C@@H:21]1[C@@H:22]([CH3:23])[C:24]([S:26][CH3:27])=[C:16]2[C:15]([O:14][CH2:11][CH:12]=[CH2:13])=[O:39])[CH3:29])([C:34]([CH3:35])([CH3:37])[CH3:36])([CH3:32])[CH3:33]Komponenten
5
Edukt 3
HCID 31215Triethyl phosphite
HCID 86747781(3S,4S)-1-(allyloxyoxalyl)-3-[(1R)-1-(tert-butyldimethylsilyloxy)ethyl]-4-[(1R)-1-{(methylthio)thiocarbonyl}ethyl]-2-oxoazetidine
HCID 86747782(3S,4S)-1-(allyloxyoxalyl)-3-[(1R)-1-(tert-butyldimethylsilyloxy)ethyl]-4-[(1S)-1-{(methylthio)thiocarbonyl}ethyl]-2-oxoazetidine
