(E)-N-(6,6-Dimethyl-2-hepten-4-ynyl)-N-ethyl-3-hydroxybenzylamine → (E,E)-N-ethyl-N-(6,6-dimethyl-2-hepten-4-ynyl)-3-[4-(3-thienyl)-3-butenyloxy]benzylamine

HRID 1464744Notizen

Reaktionsgleichung

Reaktionsgleichung von HRID 1464744
CN(CC1C=CC=C(O)C=1)C/C=C/C#CC(C)(C)C.[S:20]1[CH:24]=[CH:23][C:22](/[CH:25]=[CH:26]/[CH2:27][CH2:28][OH:29])=[CH:21]1.[CH2:30]([N:32]([CH2:42][C:43]1[CH:48]=[CH:47][CH:46]=[C:45](O)[CH:44]=1)[CH2:33]/[CH:34]=[CH:35]/[C:36]#[C:37][C:38]([CH3:41])([CH3:40])[CH3:39])[CH3:31]>>[CH2:30]([N:32]([CH2:42][C:43]1[CH:44]=[CH:45][CH:46]=[C:47]([O:29][CH2:28][CH2:27]/[CH:26]=[CH:25]/[C:22]2[CH:23]=[CH:24][S:20][CH:21]=2)[CH:48]=1)[CH2:33]/[CH:34]=[CH:35]/[C:36]#[C:37][C:38]([CH3:39])([CH3:40])[CH3:41])[CH3:31]

Komponenten

4

Edukt 3

HCID 10445905(E)-N-(6,6-Dimethyl-2-hepten-4-ynyl)-N-ethyl-3-hydroxybenzylamineHCID 19916986(E)-N-(6,6-dimethyl-2-hepten-4-ynyl)-N-methyl-3-hydroxybenzylamineHCID 19916993(E)-4-(3-thienyl)-3-buten-1-ol

Produkt 1

HCID 19917035(E,E)-N-ethyl-N-(6,6-dimethyl-2-hepten-4-ynyl)-3-[4-(3-thienyl)-3-butenyloxy]benzylamine

Versuchsvorschrift

Compounds of Examples 63 and 64 were obtained by performing the same reaction as in Example 62 except that 2-(3-thienymethoxy)ethanol or (E)-N-methyl-N-(6,6-dimethyl-2-hepten-4-ynyl)-3-hydroxybenzylamine was used instead of the starting compound, (E)-4-(3-thienyl)-3-buten-1-ol or (E)-N-ethyl-N-(6,6-dimethyl-2-hepten-4-ynyl)-3-hydroxybenzylamine, which was used in the above-mentioned reaction.

Aufarbeitung

  1. customwas used in the above-mentioned reaction

Quellen und Nachweise

ORD-Eintrag
ord-9843a335f13f45f5a610f6dee5075e5a
Quelldatensatz
uspto-grants-1994_04
Patentnummer
US05306728

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