Tetrahydrofuran → HCID 131731270, Verbindung

HRID 1475591Notizen

Reaktionsgleichung

Reaktionsgleichung von HRID 1475591
[I-:1].[La+3:2].[I-].[I-].[C:5]([C:9]1[N-:10][C:11]([C:19]([CH3:23])([CH3:22])[CH2:20][CH3:21])=[C:12]([C:14]([CH3:18])([CH3:17])[CH2:15][CH3:16])[N:13]=1)([CH3:8])([CH3:7])[CH3:6].[K+].[CH2:25]1[CH2:29][O:28][CH2:27][CH2:26]1>>[O:28]1[CH2:29][CH2:25][CH2:26][CH2:27]1.[O:28]1[CH2:29][CH2:25][CH2:26][CH2:27]1.[I-:1].[I-:1].[C:5]([C:9]1[N-:13][C:12]([C:14]([CH3:17])([CH3:18])[CH2:15][CH3:16])=[C:11]([C:19]([CH3:23])([CH3:22])[CH2:20][CH3:21])[N:10]=1)([CH3:8])([CH3:7])[CH3:6].[La+3:2]

Komponenten

4

Edukt 3

HCID 8028TetrahydrofuranHCID 25210651LANTHANUM IODIDEHCID 131731268HCID 131731268, Verbindung

Produkt 1

HCID 131731270HCID 131731270, Verbindung

Versuchsvorschrift

Lanthanum (III) iodide (1.0 g, 0.002 mol) was stirred in 50 mL of THF for 30 mins at room temperature. Potassium 2-tert-butyl-4,5-di-(1,1-dimethylpropyl)imidazolate (0.6 g, 0.002 mol) was added, and the resulting mixture was refluxed for 60 hours. THF was removed by vacuum, followed by hexane extraction, then filtration. The hexane was removed by vacuum, and the resulting solid was crystallized to isolate the final product.

Aufarbeitung

  1. temperaturethe resulting mixture was refluxed for 60 hours
  2. customTHF was removed by vacuum
  3. extractionfollowed by hexane extraction
  4. filtrationfiltration
  5. customThe hexane was removed by vacuum
  6. customthe resulting solid was crystallized

Quellen und Nachweise

ORD-Eintrag
ord-11fdc88107d7442a869453ade4d25830
Quelldatensatz
uspto-grants-2015_04
Patentnummer
US09018387B2

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