Reaktionsgleichung
[C:1]([O:4][C:5]1[CH:10]=[CH:9][CH:8]=[CH:7][CH:6]=1)(=O)[CH3:2].[CH2:11]1[CH2:16]CC[CH2:13][CH2:12]1.C(OOC(C)(C)C)(C)(C)C>>[C:1]1([O:4][CH:5]2[CH2:10][CH2:9][CH2:8][CH2:7][CH2:6]2)[CH:13]=[CH:12][CH:11]=[CH:16][CH:2]=1Komponenten
4
Reaktionsbedingungen
- Temperatur
- 90 °C
Versuchsvorschrift
Into a pressure vessel phenyl acetate (126 μL, 1 mmol, 1 eq) was added and diluted with cyclohexane (1.080 mL, 10 mmol, 10 eq). To this stirring solution was added 1 mol % of a stock solution of {[Cl2NN]Cu}2(benzene) from the catalyst stock solution described in Example 4 (200 μL=0.01 mmol). After adding of tert-butyl peroxide (220 μL, 1.2 mmol), the pressure vessel was sealed and heated to 90° C. for 24 hr. The catalyst was separated by exposing the mixture to air and filtering through Celite®. After removing cyclohexane under vacuum, the residue was analyzed by 1H NMR and GC/MS to determine the yield and consumption of starting materials.
Aufarbeitung
- customthe pressure vessel was sealed
- customThe catalyst was separated
- filtrationfiltering through Celite®
- customAfter removing cyclohexane under vacuum
- customyield
- customconsumption of starting materials
Quellen und Nachweise
- ORD-Eintrag
- ord-4fcaf084be86445296ae50a01f11db1d
- Quelldatensatz
- uspto-grants-2016_08
- Patentnummer
- US09416080B2
Verknüpfte Notizen
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