Methyl 3,5-Dihydroxybenzoate → 3,5-Bis[3-(1,1'-biphenyl-2-yloxy)propoxy]benzoic acid methyl ester
Reaktionsgleichung
[CH3:1][O:2][C:3](=[O:12])[C:4]1[CH:9]=[C:8]([OH:10])[CH:7]=[C:6]([OH:11])[CH:5]=1.Br[CH2:14][CH2:15][CH2:16][O:17][C:18]1[CH:23]=[CH:22][CH:21]=[CH:20][C:19]=1[C:24]1[CH:29]=[CH:28][CH:27]=[CH:26][CH:25]=1>>[CH3:1][O:2][C:3](=[O:12])[C:4]1[CH:5]=[C:6]([O:11][CH2:14][CH2:15][CH2:16][O:17][C:18]2[CH:23]=[CH:22][CH:21]=[CH:20][C:19]=2[C:24]2[CH:29]=[CH:28][CH:27]=[CH:26][CH:25]=2)[CH:7]=[C:8]([O:10][CH2:14][CH2:15][CH2:16][O:17][C:18]2[CH:23]=[CH:22][CH:21]=[CH:20][C:19]=2[C:24]2[CH:29]=[CH:28][CH:27]=[CH:26][CH:25]=2)[CH:9]=1Komponenten
3
Versuchsvorschrift
Using this procedure, the reaction of 3,5-dihydroxybenzoic acid methyl ester with 2-(3-bromopropoxy)-1,1-biphenyl gave 3,5-bis[3-(1,1'-biphenyl-2-yloxy)propoxy]benzoic acid methyl ester, mp 77°-79°. Anal. Calcd for C38H36O6 : C, 77.53; H, 6.16. Found: C, 77.31; H, 6.15.
Quellen und Nachweise
- ORD-Eintrag
- ord-2c73d7bf22eb4429a5973389eb4dea1f
- Quelldatensatz
- uspto-grants-1994_12