HuagongsheHuagongshe Chemie-Druckbericht · Nur für Forschungszwecke
2-Chlorotoluene → 2,2'-Dimethylbiphenyl
Beteiligte Stoffe
| Rolle | Name | HCID | Einwaage |
|---|---|---|---|
| Edukt | 2-Chlorotoluene | HCID 7238 | — |
| Edukt | Tetrahydrofuran | HCID 8028 | — |
| Edukt | HCID 178418310 | HCID 178418310 | — |
| Produkt | 2,2'-Dimethylbiphenyl | HCID 11797 | — |
Reaktionsschritte
All of the following runs were made with 1 mmol NiBr2 and 24 mmol t-butylmagnesium chloride in THF at reflux for 16 hours. Protic ligands were converted to their magnesium salts by the addition of an equivalent amount of a Grignard reagent prior to addition of 2-chlorotoluene.
Herkunft & Nachweise
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patentnummer | US05021380 |
| Quelldatensatz | uspto-grants-1991_06 |
| ORD ID | ord-03e5f6c8a9ce4868b0f6ed5a06d7f26a |
| Quellennotiz | uspto-grants-1991_06 |