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HuagongsheHuagongshe Chemie-Druckbericht · Nur für Forschungszwecke
HRID 1493109Erstellt: 27. Oktober 2026

2-Chlorotoluene → 2,2'-Dimethylbiphenyl

https://huagongshe.com/reaction/1493109

Reaktionsgleichung

Beteiligte Stoffe

RolleNameHCIDEinwaage
Edukt2-ChlorotolueneHCID 7238—
EduktTetrahydrofuranHCID 8028—
EduktHCID 178418310HCID 178418310—
Produkt2,2'-DimethylbiphenylHCID 11797—

Reaktionsschritte

All of the following runs were made with 1 mmol NiBr2 and 24 mmol t-butylmagnesium chloride in THF at reflux for 16 hours. Protic ligands were converted to their magnesium salts by the addition of an equivalent amount of a Grignard reagent prior to addition of 2-chlorotoluene.

Herkunft & Nachweise

DOI10.6084/m9.figshare.5104873.v1
PatentnummerUS05021380
Quelldatensatzuspto-grants-1991_06
ORD IDord-03e5f6c8a9ce4868b0f6ed5a06d7f26a
Quellennotizuspto-grants-1991_06