2-Methyl-dibenzothiophene → 2-Nitrodibenzothiophene
Reaktionsgleichung
C1C2C3C(C=C4C=2C=CC=C4)=CC=CC=3C=C1.[N+:18]([C:21]1[CH:22]=[CH:23][C:24]2C=CCC3=C4C(=C[C:34]=1[C:25]=23)C=CC=C4)([O-:20])=[O:19].C[C:39]1[CH:51]=[CH:50][C:42]2[S:43]C3C=CC=CC=3[C:41]=2[CH:40]=1>>[N+:18]([C:21]1[CH:22]=[CH:23][C:24]2[S:43][C:42]3[CH:50]=[CH:51][CH:39]=[CH:40][C:41]=3[C:25]=2[CH:34]=1)([O-:20])=[O:19]Komponenten
4
Versuchsvorschrift
For example, as a result of the nitration, the reaction between the 1H-benzo[de]anthracene of the asphaltene polycyclic core forms 6-nitro-1H-benzo[de]anthracene (19) and the nitration reaction with 2-methyldibenzo[b,d]thiophene yields 2-nitrodibenzo[b,d]thiophene (20).
Quellen und Nachweise
- ORD-Eintrag
- ord-81859aac091940fe96281dd806a2bd66
- Quelldatensatz