Carbon Tetrachloride → Ethyl 2-chloro-2-(o-tolylimino)acetate

HRID 1506628Notizen

Reaktionsgleichung

Reaktionsgleichung von HRID 1506628
O=[C:2]([NH:8][C:9]1[CH:14]=[CH:13][CH:12]=[CH:11][C:10]=1[CH3:15])[C:3]([O:5][CH2:6][CH3:7])=[O:4].C1(P(C2C=CC=CC=2)C2C=CC=CC=2)C=CC=CC=1.C(Cl)(Cl)(Cl)[Cl:36]>>[Cl:36][C:2](=[N:8][C:9]1[CH:14]=[CH:13][CH:12]=[CH:11][C:10]=1[CH3:15])[C:3]([O:5][CH2:6][CH3:7])=[O:4]

Komponenten

4

Edukt 3

HCID 5943Carbon TetrachlorideHCID 11776TriphenylphosphineHCID 366755Ethyl [(2-methylphenyl)amino](oxo)acetate

Produkt 1

HCID 90280270Ethyl 2-chloro-2-(o-tolylimino)acetate

Versuchsvorschrift

The suspension of ethyl 2-oxo-2-(o-tolylamino)acetate (2.0 g, 10 mmol) and triphenylphosphine (4.0 g, 15 mmol) in carbon tetrachloride (150 mL) was refluxed overnight. The reaction was cooled down and filtered. The filtrate was collected and concentrated and used it without further purification. MS (m/z) 226 [M+H]+.

Aufarbeitung

  1. temperaturewas refluxed overnight
  2. temperatureThe reaction was cooled down
  3. filtrationfiltered
  4. customThe filtrate was collected
  5. concentrationconcentrated
  6. customwithout further purification

Quellen und Nachweise

ORD-Eintrag
ord-e2541b6eee964802a631689e192c3bde
Quelldatensatz
uspto-grants-2015_12
Patentnummer
US09220710B2

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