12-Hydroxydodecanoic Acid → Lauric Acid

HRID 1509354

Reaktionsgleichung

Reaktionsgleichung von HRID 1509354
O[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][C:13]([OH:15])=[O:14].OC(CCCCCCCCCC)C(O)=O.OC(CCCCCCCCC)CC(O)=O>>[C:13]([OH:15])(=[O:14])[CH2:12][CH2:11][CH2:10][CH2:9][CH2:8][CH2:7][CH2:6][CH2:5][CH2:4][CH2:3][CH3:2]

Komponenten

4

Edukt 3

HCID 7903412-Hydroxydodecanoic AcidHCID 94216(+-)-3-Hydroxydodecanoic acidHCID 97783Hydroxylauric Acid

Produkt 1

HCID 3893Lauric Acid

Versuchsvorschrift

A product peak appeared in the presence of the peroxygenase. The elution time of the product was slightly shifted compared to 12-Hydroxydodecanoic acid, which is an iso-form of 2-hydroxy lauric acid and 3-hydroxy lauric acid. Hence, the elution time was in accordance to the expected product hydroxylated in the 2 or 3 position.

Quellen und Nachweise

ORD-Eintrag
ord-47efaaa3ca4c440bbe18f397ee5918ca
Quelldatensatz
uspto-grants-2015_12
Patentnummer
US09222109B2

Verknüpfte Notizen

Wird geladen…