4-amino-N-(3,4-dimethylphenyl)-3-nitrobenzamide → HCID 66965643, Verbindung

HRID 1514890Notizen

Reaktionsgleichung

Reaktionsgleichung von HRID 1514890
[NH2:1][C:2]1[CH:18]=[CH:17][C:5]([C:6]([NH:8][C:9]2[CH:14]=[CH:13][C:12]([CH3:15])=[C:11]([CH3:16])[CH:10]=2)=[O:7])=[CH:4][C:3]=1[N+:19]([O-])=O>C(O)C.[Pt]=O>[NH2:19][C:3]1[CH:4]=[C:5]([CH:17]=[CH:18][C:2]=1[NH2:1])[C:6]([NH:8][C:9]1[CH:14]=[CH:13][C:12]([CH3:15])=[C:11]([CH3:16])[CH:10]=1)=[O:7]

Komponenten

4

Edukt 1

HCID 87439264-amino-N-(3,4-dimethylphenyl)-3-nitrobenzamide

Produkt 1

HCID 66965643HCID 66965643, Verbindung

Reagenzien, Katalysatoren, Lösungsmittel 2

HCID 82844Platinum oxide (PtO)KatalysatorHCID 702EthanolLösungsmittel

Versuchsvorschrift

A suspension of give 4-amino-N-(3,4-dimethyl-phenyl)-3-nitro-benzamide (560 mg) and platinum oxide (50 mg) in ethanol (50 mL) was hydrogenated at 50 psi for 3 h. The catalyst was filtered through Celite and the filtrate evaporated to give 3,4-diamino-N-(3,4-dimethylphenyl)-benzamide as a brownish foam; MS (m/z) 256 (M+1).

Aufarbeitung

  1. filtrationThe catalyst was filtered through Celite
  2. customthe filtrate evaporated

Quellen und Nachweise

ORD-Eintrag
ord-16163c71d88f484c86dadde8f3a63320
Quelldatensatz
uspto-grants-2012_07
Patentnummer
US08222248B2

Notizen zur Reaktion

Wird geladen…