5-chloro-1-(2-phenylethyl)-1H-indole-2,3-dione → 5-Chloro-2-oxo-1-phenethylindolin-3-yl benzoate
Reaktionsgleichung
[C:1](OC1C2C(=CC=C(C)C=2)N(CC)C1=O)(=[O:8])[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1.[Cl:23][C:24]1[CH:25]=[C:26]2[C:30](=[CH:31][CH:32]=1)[N:29]([CH2:33][CH2:34][C:35]1[CH:40]=[CH:39][CH:38]=[CH:37][CH:36]=1)[C:28](=[O:41])[C:27]2=[O:42]>>[C:1]([O:42][CH:27]1[C:26]2[C:30](=[CH:31][CH:32]=[C:24]([Cl:23])[CH:25]=2)[N:29]([CH2:33][CH2:34][C:35]2[CH:40]=[CH:39][CH:38]=[CH:37][CH:36]=2)[C:28]1=[O:41])(=[O:8])[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1Komponenten
3
Versuchsvorschrift
Was made in an analogous fashion to 1-ethyl-5-methyl-2-oxoindolin-3-yl benzoate using 5-chloro-1-phenethylindoline-2,3-dione. 1H-NMR δ 8.11 (dd, 2H), 7.60 (dt, 1H), 7.47 (m, 2H), 7.41 (dd, 1H), 7.34-7.24 (m, 6H), 6.68 (d, 1H), 6.07 (s, 1H), 3.97 (dd, 2H), 3.02 (t, 2H).
Quellen und Nachweise
- ORD-Eintrag
- ord-2af888a18eb54e39a440f32c48492c18
- Quelldatensatz
- uspto-grants-2015_07