5-Methyl-1-(4-methylpentyl)indoline-2,3-dione → 5-Methyl-1-(4-methylpentyl)-2-oxoindolin-3-yl benzoate
Reaktionsgleichung
[C:1](OC1C2C(=CC=CC=2)N(CCC)C1=O)(=[O:8])[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1.[CH3:23][C:24]1[CH:25]=[C:26]2[C:30](=[CH:31][CH:32]=1)[N:29]([CH2:33][CH2:34][CH2:35][CH:36]([CH3:38])[CH3:37])[C:28](=[O:39])[C:27]2=[O:40]>>[C:1]([O:40][CH:27]1[C:26]2[C:30](=[CH:31][CH:32]=[C:24]([CH3:23])[CH:25]=2)[N:29]([CH2:33][CH2:34][CH2:35][CH:36]([CH3:37])[CH3:38])[C:28]1=[O:39])(=[O:8])[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1Komponenten
3
Versuchsvorschrift
Was made in a similar way to 2-oxo-1-propylindolin-3-yl benzoate starting from 5-methyl-1-(4-methylpentyl)indoline-2,3-dione. 1H-NMR δ 8.11 (d, 2H), 7.58 (dt, 1H), 7.45 (m, 2H), 7.25 (s, 1H), 7.15 (dd, 1H), 6.77 (d, 1H), 6.17 (s, 1H), 3.70 (m, 2H), 2.31 (s, 3H), 1.73 (m, 2H), 1.61 (m, 1H), 1.29 (m, 2H), 0.90 (d, 6H).
Quellen und Nachweise
- ORD-Eintrag
- ord-ccaae662ec7e44fabd98afdf832300b8
- Quelldatensatz
- uspto-grants-2015_07