Benzyl methyl(15-phenylpentadec-5-en-1-yl)carbamate → N-methyl-15-phenylpentadecane-1-amine

HRID 1525801Notizen

Reaktionsgleichung

Reaktionsgleichung von HRID 1525801
[CH3:1][N:2]([CH2:13][CH2:14][CH2:15][CH2:16][CH:17]=[CH:18][CH2:19][CH2:20][CH2:21][CH2:22][CH2:23][CH2:24][CH2:25][CH2:26][CH2:27][C:28]1[CH:33]=[CH:32][CH:31]=[CH:30][CH:29]=1)C(=O)OCC1C=CC=CC=1>C(O)C.[C].[Pd]>[CH3:1][NH:2][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][CH2:22][CH2:23][CH2:24][CH2:25][CH2:26][CH2:27][C:28]1[CH:29]=[CH:30][CH:31]=[CH:32][CH:33]=1

Komponenten

4

Edukt 1

HCID 86722744Benzyl methyl(15-phenylpentadec-5-en-1-yl)carbamate

Produkt 1

HCID 86722746N-methyl-15-phenylpentadecane-1-amineAusbeute 65,4 %

Reagenzien, Katalysatoren, Lösungsmittel 2

HCID 178418390HCID 178418390, VerbindungKatalysatorHCID 702EthanolLösungsmittel

Versuchsvorschrift

Compound 15 (2.6 g) was dissolved in ethanol (20 mL) and 5% palladium carbon (260 mg) was added thereto, followed by stirring at room temperature for 3.5 hours under hydrogen atmosphere. The reaction solution was replaced with argon atmosphere, filtered with Celite (brand name) and concentrated under reduced pressure to obtain the title compound (1.2 g) having the following physical property values.

Aufarbeitung

  1. filtrationfiltered with Celite (brand name)
  2. concentrationconcentrated under reduced pressure

Quellen und Nachweise

ORD-Eintrag
ord-7150da1bcaca4e0598449b3849a594d1
Quelldatensatz
uspto-grants-2015_07
Patentnummer
US09085523B2

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