Zurück
HuagongsheHuagongshe Chemie-Druckbericht · Nur für Forschungszwecke
HRID 15291Erstellt: 25. Oktober 2026

Benzyl mercaptan → (R)-3-Benzylsulfanyl-2-hydroxy-propionic acid methyl ester

https://huagongshe.com/reaction/15291

Reaktionsgleichung

Beteiligte Stoffe

RolleNameHCIDEinwaage
EduktBenzyl mercaptanHCID 7509—
EduktMethyl (2S)-2-oxiranecarboxylateHCID 10942355—
Produkt(R)-3-Benzylsulfanyl-2-hydroxy-propionic acid methyl esterHCID 5963932292%

Reaktionsschritte

This reaction was performed as previously described by Deechongkit, S.; You, S.-L.; Kelly, J. W. Org. Lett. 2004, 6, 497, using (S)-Methylglycidate 110a and Benzyl mercaptan. (R)-3-Benzylsulfanyl-2-hydroxy-propionic acid methyl ester 110b (7.41 g, 31.41 mmol, 92%) was isolated as a viscous oil: MS calcd. for C11H14O3S (M+H+) 227.1, found 227.3.

Herkunft & Nachweise

DOI10.6084/m9.figshare.5104873.v1
PatentnummerUS07732449B2
Quelldatensatzuspto-grants-2010_06
ORD IDord-27bc3950df9e4290b5641d3488fcb1c7
Quellennotizuspto-grants-2010_06