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HuagongsheHuagongshe Chemie-Druckbericht · Nur für Forschungszwecke
HRID 1530810Erstellt: 27. Oktober 2026

Dimethyl (4-hydroxyphenyl)malonate → Dimethyl (4-hydroxycyclohexyl)malonate

https://huagongshe.com/reaction/1530810

Reaktionsgleichung

Beteiligte Stoffe

RolleNameHCIDEinwaage
EduktDimethyl (4-hydroxyphenyl)malonateHCID 3018973—
EduktHCID 178418361HCID 178418361—
KatalysatorRhodiumHCID 23948—
LösungsmittelMethanolHCID 887—
ProduktDimethyl (4-hydroxycyclohexyl)malonateHCID 91368111—

Reaktionsschritte

At 60° C. and a hydrogen pressure of 150 bar, 67.3 g of dimethyl (4-hydroxyphenyl)malonate in 500 ml of methanol were hydrogenated in the presence of 5 g of rhodium/carbon catalyst (5%). The catalyst was filtered off and the mixture was concentrated. This to give the title product as a colourless oil.

Herkunft & Nachweise

DOI10.6084/m9.figshare.5104873.v1
PatentnummerUS06197729B1
Quelldatensatzuspto-grants-2001_03
ORD IDord-680e2cf6c9d64e7d9dcd6c264458d4fe
Quellennotizuspto-grants-2001_03