N1,N1-Dimethyl-N3-(2-nitrophenyl)-1,3-propanediamine → N~1~-[3-(Dimethylamino)propyl]benzene-1,2-diamine

HRID 1532639Notizen

Reaktionsgleichung

Reaktionsgleichung von HRID 1532639
[CH3:1][N:2]([CH3:16])[CH2:3][CH2:4][CH2:5][NH:6][C:7]1[CH:12]=[CH:11][CH:10]=[CH:9][C:8]=1[N+:13]([O-])=O>C(O)C.[C].[Pd]>[CH3:16][N:2]([CH3:1])[CH2:3][CH2:4][CH2:5][NH:6][C:7]1[C:8]([NH2:13])=[CH:9][CH:10]=[CH:11][CH:12]=1

Komponenten

4

Edukt 1

HCID 210504N1,N1-Dimethyl-N3-(2-nitrophenyl)-1,3-propanediamine

Produkt 1

HCID 14174121N~1~-[3-(Dimethylamino)propyl]benzene-1,2-diamineAusbeute 100,1 %

Reagenzien, Katalysatoren, Lösungsmittel 2

HCID 178418390HCID 178418390, VerbindungKatalysatorHCID 702EthanolLösungsmittel

Versuchsvorschrift

10% of palladium-carbon (0.18 g) was added to a solution containing N1,N1-dimethyl-N3-(2-nitrophenyl)-1,3-propanediamine (0.90 g) in ethanol (9 ml) and stirred for 2.5 hours under a hydrogen gas atmosphere at room temperature. After the catalyst was removed out by filtration, the filtrate was concentrated, thereby yielding the entitled compound (0.78 g) as reddish brown oil.

Aufarbeitung

  1. customAfter the catalyst was removed out by filtration
  2. concentrationthe filtrate was concentrated

Quellen und Nachweise

ORD-Eintrag
ord-78640b95da544b988deb1b71a3fca6fa
Quelldatensatz
uspto-grants-2001_03
Patentnummer
US06204264B1

Notizen zur Reaktion

Wird geladen…