N,N-Dimethylethylenediamine → HCID 22013736, Verbindung

HRID 1532689Notizen

Reaktionsgleichung

Reaktionsgleichung von HRID 1532689
[CH3:1][N:2]([CH3:6])[CH2:3][CH2:4][NH2:5].Cl[C:8]1[CH:17]=[CH:16][C:11]([C:12]([NH:14][CH3:15])=[O:13])=[CH:10][C:9]=1[N+:18]([O-:20])=[O:19]>C(OCC)(=O)C>[CH3:1][N:2]([CH3:6])[CH2:3][CH2:4][NH:5][C:8]1[CH:17]=[CH:16][C:11]([C:12]([NH:14][CH3:15])=[O:13])=[CH:10][C:9]=1[N+:18]([O-:20])=[O:19]

Komponenten

4

Edukt 2

HCID 66053N,N-DimethylethylenediamineHCID 7992864-chloro-N-methyl-3-nitrobenzamide

Produkt 1

HCID 22013736HCID 22013736, Verbindung

Reagenzien, Katalysatoren, Lösungsmittel 1

HCID 8857Ethyl AcetateLösungsmittel

Reaktionsbedingungen

Temperatur
100 °C

Versuchsvorschrift

N,N-Dimethylethylenediamine (3.30 ml) was added to 4-chloro-N-methyl-3-nitrobenzamide (3.220 g) and the mixture was stirred for 14 hours at 100° C. The reaction mixture, with ethyl acetate added thereto, was washed with 1N sodium hydroxide aqueous solution and saturated brine successively, dried over sodium sulfate anhydride, and concentrated, thereby yielding the entitled compound (3.687 g) as yellowish orange solid.

Aufarbeitung

  1. washwas washed with 1N sodium hydroxide aqueous solution and saturated brine successively
  2. dry with materialdried over sodium sulfate anhydride
  3. concentrationconcentrated

Quellen und Nachweise

ORD-Eintrag
ord-654257d6142042fdb74bfa23f2db7568
Quelldatensatz
uspto-grants-2001_03
Patentnummer
US06204264B1

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