Mesityl oxide → 2-Methyl-2-(1,1,3,3-tetramethylbutylperoxy)-4-pentanone

HRID 1577961Notizen

Reaktionsgleichung

Reaktionsgleichung von HRID 1577961
[O:1]=[C:2]([CH:4]=[C:5]([CH3:7])[CH3:6])[CH3:3].[CH3:8][C:9]([O:16][OH:17])([CH3:15])[CH2:10][C:11]([CH3:14])([CH3:13])[CH3:12]>>[CH3:6][C:5]([O:17][O:16][C:9]([CH3:15])([CH3:8])[CH2:10][C:11]([CH3:14])([CH3:13])[CH3:12])([CH2:4][C:2](=[O:1])[CH3:3])[CH3:7]

Komponenten

3

Edukt 2

HCID 8858Mesityl oxideHCID 798771,1,3,3-Tetramethylbutyl hydroperoxide

Produkt 1

HCID 205704772-Methyl-2-(1,1,3,3-tetramethylbutylperoxy)-4-pentanone

Reaktionsbedingungen

Temperatur
25 °C

Versuchsvorschrift

A mixture of 49 g (0.50 mole) of mesityl oxide and 10 g of Amberlyst 15® sulfonic acid type ion-exchange resin was stirred at 0°-5° C., while 78 g (0.45 mole) of 84% 1,1,3,3-tetramethylbutyl hydroperoxide was added slowly. The reaction mixture was allowed to warm to 25° C. and the stirring continued for 16 hours. The ion-exchange resin was separated by filtration. Iodometric assay showed that substantially all of the hydroperoxide had reacted. The infrared spectrum and G.L.C. showed the presence of the desired product.

Aufarbeitung

  1. additionwas added slowly
  2. customThe ion-exchange resin was separated by filtration
  3. customhad reacted

Quellen und Nachweise

ORD-Eintrag
ord-fb04a607173249e9afb9ef2a40493b4b
Quelldatensatz
uspto-grants-1981_09
Patentnummer
US04289914

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