HuagongsheHuagongshe Chemie-Druckbericht · Nur für Forschungszwecke
D-Glucose → Nitrous acid, hexyl ester
Beteiligte Stoffe
| Rolle | Name | HCID | Einwaage |
|---|---|---|---|
| Edukt | D-Glucose | HCID 5793 | — |
| Edukt | 1-Bromohexane | HCID 8101 | — |
| Edukt | 1-Nitrohexane | HCID 12589 | — |
| Edukt | Tris(dimethylamino)sulfonium nitrite | HCID 21557485 | — |
| Lösungsmittel | Acetonitrile | HCID 6342 | — |
| Produkt | Nitrous acid, hexyl ester | HCID 6365123 | — |
Reaktionsschritte
A 165-mg (1 mmole) sample of 1-bromohexane was added to 0.5 ml (1 mmole) of 2M tris(dimethylamino)sulfonium nitrite in acetonitrile. The course of the reaction was followed by glc analysis. No further reaction occurred after 15 min. Glc analysis showed that 1-nitrohexane and 1-hexyl nitrite were formed in a 70:30 ratio.
Herkunft & Nachweise
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patentnummer | US03940402 |
| Quelldatensatz | uspto-grants-1976_02 |
| ORD ID | ord-b299314bb2084a96854535dde897a5ae |
| Quellennotiz | uspto-grants-1976_02 |