2,6,6-Trimethyl-1-(1-hydroxy-3-butenyl)-1-cyclohexene → 2,6,6-Trimethyl-1-[3-methyl-3-butenoyl]-1-cyclohexene

HRID 1579793Notizen

Reaktionsgleichung

Reaktionsgleichung von HRID 1579793
CC1CCCC(C)(C)C=1C(O)CC=C.[CH3:15][C:16]1[CH2:21][CH2:20][CH2:19][C:18]([CH3:23])([CH3:22])[C:17]=1[CH:24]([OH:29])[CH2:25][C:26]([CH3:28])=[CH2:27]>>[CH3:15][C:16]1[CH2:21][CH2:20][CH2:19][C:18]([CH3:22])([CH3:23])[C:17]=1[C:24](=[O:29])[CH2:25][C:26]([CH3:28])=[CH2:27]

Komponenten

3

Edukt 2

HCID 124203212,6,6-Trimethyl-1-(1-hydroxy-3-butenyl)-1-cyclohexeneHCID 233380582,6,6-Trimethyl-1-[1-hydroxy-3-methyl-3-butenyl]-1-cyclohexene

Produkt 1

HCID 233380842,6,6-Trimethyl-1-[3-methyl-3-butenoyl]-1-cyclohexene

Versuchsvorschrift

By replacing hereabove 2,6,6-trimethyl-1-[1-hydroxy-3-butenyl]-1-cyclohexene with 2,6,6-trimethyl-1-[1-hydroxy-3-methyl-3-butenyl]-1-cyclohexene (nD20 = 1.4939; d420 = 0.9270), 2,6,6-trimethyl-1-[3-methyl-3-butenoyl]-1-cyclohexene was obtained; nD20 = 1.4862; d420 = 0.9307.

Quellen und Nachweise

ORD-Eintrag
ord-f337919723564119b6fd3a03b3cdccf4
Quelldatensatz
uspto-grants-1976_01
Patentnummer
US03931326

Notizen zur Reaktion

Wird geladen…