Allyl Mercaptan → Pyridazine, 3-(2-propenylthio)-6-propoxy-
Reaktionsgleichung
[Na].[CH2:2]([SH:5])[CH:3]=[CH2:4].[CH2:6]([O:9][C:10]1[N:11]=[N:12][C:13](Cl)=[CH:14][CH:15]=1)[CH2:7][CH3:8]>CO>[CH2:6]([O:9][C:10]1[N:11]=[N:12][C:13]([S:5][CH2:2][CH:3]=[CH2:4])=[CH:14][CH:15]=1)[CH2:7][CH3:8]Komponenten
5
Edukt 3
Produkt 1
Reagenzien, Katalysatoren, Lösungsmittel 1
Versuchsvorschrift
1.15 g(0.05 mol) of metallic sodium was dissolved in 75 ml of absolute methanol and then mixed with 4.98 ml(0.05 mol) of allylmercaptan. To this mixture was added 8.63 g(0.05 mol) of 3-(n-propoxy)-6-chloropyridazine. The reaction solution was refluxed for 24 hours and then treated according to the same manner as Example 1 to obtain the title compound as a pale yellow oily residue.
Aufarbeitung
- temperatureThe reaction solution was refluxed for 24 hours
- additiontreated
Quellen und Nachweise
- ORD-Eintrag
- ord-0a471fdb725042d98a5fc22967d9fb5c
- Quelldatensatz
- uspto-grants-1999_08
- Patentnummer
- US05942511
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