HuagongsheHuagongshe Chemie-Druckbericht · Nur für Forschungszwecke
1-Decene → Methyltridecylsilane
Beteiligte Stoffe
| Rolle | Name | HCID | Einwaage |
|---|---|---|---|
| Edukt | 1-Decene | HCID 13381 | — |
| Edukt | Methyldidecylsilane | HCID 71366123 | — |
| Katalysator | Carbonylhydridotris(triphenylphosphine)rhodium(I) | HCID 10941995 | — |
| Lösungsmittel | Benzene | HCID 241 | — |
| Produkt | Methyltridecylsilane | HCID 123907608 | 85% |
Reaktionsschritte
A mixture of 1.53 grams of methyldidecylsilane, and 0.70 gram of 1-decene in 5 milliliters of benzene was reacted for 25 hours at 50° C. in the presence of 0.005 gram hydridocarbonyltris(triphenylphosphine)rhodium(I). Chromatographic analysis showed that an 85 percent yield of methyltridecylsilane was formed at a 65 percent silane conversion.
Herkunft & Nachweise
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patentnummer | US04572791 |
| Quelldatensatz | uspto-grants-1986_02 |
| ORD ID | ord-41f29fe13006406dbcfb4c156e765557 |
| Quellennotiz | uspto-grants-1986_02 |