4-Pyridinecarboxaldehyde → 2-(1-Methoxyiminoindan-5-yl)-4-(2-methylsulfanylpyrimidin-5-yl)-1-pyridin-4-ylbutane-1,4-dione
Reaktionsgleichung
[CH3:1][O:2][N:3]=[C:4]1[C:12]2[C:7](=[CH:8][C:9](/[CH:13]=[CH:14]/[C:15]([C:17]3[CH:18]=[N:19][C:20]([S:23][CH3:24])=[N:21][CH:22]=3)=[O:16])=[CH:10][CH:11]=2)[CH2:6][CH2:5]1.[N:25]1[CH:30]=[CH:29][C:28]([CH:31]=[O:32])=[CH:27][CH:26]=1>>[CH3:1][O:2][N:3]=[C:4]1[C:12]2[C:7](=[CH:8][C:9]([CH:13]([CH2:14][C:15]([C:17]3[CH:18]=[N:19][C:20]([S:23][CH3:24])=[N:21][CH:22]=3)=[O:16])[C:31]([C:28]3[CH:29]=[CH:30][N:25]=[CH:26][CH:27]=3)=[O:32])=[CH:10][CH:11]=2)[CH2:6][CH2:5]1Komponenten
3
Versuchsvorschrift
The title compound (2.9 g, 74%) was prepared from the product of Step 2 and 4-pyridinecarboxaldehyde using the method of Example 1 Step 4; MS(ES+) m/e 447 [M+H]+.
Quellen und Nachweise
- ORD-Eintrag
- ord-0a5a12fb68a54214a6d8eb72107b4236