Aluminum(III) Chloride → HCID 21707192, Verbindung

HRID 1594934Notizen

Reaktionsgleichung

Reaktionsgleichung von HRID 1594934
[CH3:1][O:2][C:3]1[CH:4]=[C:5]2[C:10](=[C:11]([O:13]C)[CH:12]=1)[C:9](=[O:15])[CH2:8][CH2:7][CH2:6]2.[Al+3].[Cl-].[Cl-].[Cl-]>C(Cl)Cl>[OH:13][C:11]1[CH:12]=[C:3]([O:2][CH3:1])[CH:4]=[C:5]2[C:10]=1[C:9](=[O:15])[CH2:8][CH2:7][CH2:6]2

Komponenten

4

Edukt 2

HCID 6451240Aluminum(III) ChlorideHCID 114470756,8-dimethoxy-3,4-dihydro-2H-naphthalen-1-one

Produkt 1

HCID 21707192HCID 21707192, VerbindungAusbeute 98,6 %

Reagenzien, Katalysatoren, Lösungsmittel 1

HCID 6344DichloromethaneLösungsmittel

Versuchsvorschrift

A solution of 6,8-dimethoxy-3,4-dihydro-2H-naphthalen-1-one (15 g, 72.8 mmole), prepared according to the procedure of J. Chem. Soc., London 2782 (1955), which is incorporated herein by reference, in methylene chloride (150 mL) at 0° C. was treated portionwise with AlCl3 (14.3 g, 107 mmole), stirred for 20 h at room temperature, poured onto ice with stirring and extracted with methylene chloride when the ice melted. The extracts were washed with water and brine, dried (MgSO4) and concentrated to provide 13.8 g of the title compound.

Aufarbeitung

  1. additionpoured onto ice
  2. stirringwith stirring
  3. extractionextracted with methylene chloride when the ice
  4. washThe extracts were washed with water and brine
  5. dry with materialdried (MgSO4)
  6. concentrationconcentrated

Quellen und Nachweise

ORD-Eintrag
ord-d9c86aea544c469ebe9315f7aab64bf7
Quelldatensatz
uspto-grants-2001_09
Patentnummer
US06284796B1

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