Ethyl [1-(diphenylmethyl)azetidin-3-ylidene]acetate → HCID 54328202, Verbindung

HRID 1596182Notizen

Reaktionsgleichung

Reaktionsgleichung von HRID 1596182
[CH2:1]([O:3][C:4](=[O:23])[CH:5]=[C:6]1[CH2:9][N:8](C(C2C=CC=CC=2)C2C=CC=CC=2)[CH2:7]1)[CH3:2].[H][H]>C(O)C.[OH-].[OH-].[Pd+2]>[CH2:1]([O:3][C:4](=[O:23])[CH2:5][CH:6]1[CH2:9][NH:8][CH2:7]1)[CH3:2]

Komponenten

5

Edukt 2

HCID 53428664Ethyl [1-(diphenylmethyl)azetidin-3-ylidene]acetateHCID 178418361HCID 178418361, Verbindung

Produkt 1

HCID 54328202HCID 54328202, Verbindung

Reagenzien, Katalysatoren, Lösungsmittel 2

HCID 9942167Palladium hydroxideKatalysatorHCID 702EthanolLösungsmittel

Versuchsvorschrift

To a solution of (1-benzhydrylazetidin-3-ylidene)-acetic acid ethyl ester (5.0 g, 16 mmol) in ethanol (200 mL) was added palladium hydroxide on carbon (1.5 g). This mixture was vigorously shaken under a 50 psi hydrogen atmosphere for 24 hrs, then filtered and concentrated to give an oil, used without additional purification.

Aufarbeitung

  1. filtrationfiltered
  2. concentrationconcentrated
  3. customto give an oil
  4. customused without additional purification

Quellen und Nachweise

ORD-Eintrag
ord-0d8c71ddcce741c880b4bf11130e10cc
Quelldatensatz
uspto-grants-2001_09
Patentnummer
US06291457B1

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