alpha-Pinene, (+)- → L34Amw24TJ

HRID 1604206Notizen

Reaktionsgleichung

Reaktionsgleichung von HRID 1604206
[CH2:1](/[C:3](=[CH:6]\[CH2:7][C@@H:8]1[CH2:12][CH:11]=[C:10]([CH3:13])[C:9]1([CH3:15])[CH3:14])/[CH:4]=[O:5])[CH3:2].CC1[C@@H]2C(C)(C)[C@@H](C2)CC=1>>[CH2:1](/[C:3](=[CH:6]\[CH2:7][C@@H:8]1[CH2:12][CH:11]=[C:10]([CH3:13])[C:9]1([CH3:14])[CH3:15])/[CH2:4][OH:5])[CH3:2]

Komponenten

3

Edukt 2

HCID 82227alpha-Pinene, (+)-HCID 86755498(E)-(S)-2-Ethyl-4-(2,2,3-trimethylcyclopent-3-en-1-yl)-2-buten-1-al

Produkt 1

HCID 8030023L34Amw24TJ

Versuchsvorschrift

(E)-(S)-2-Ethyl-4-(2,2,3-trimethylcyclopent-3-en-1-yl)-2-buten-1-al synthesized from (1R,5R)-α-pinene having an optical purity of 97% e.e. (available from Aldrich) was hydrogenated in the same manner as in Example 2 to obtain the title compound.

Quellen und Nachweise

ORD-Eintrag
ord-f83347d47fab4e08a1550db7d889e080
Quelldatensatz
uspto-grants-1999_11
Patentnummer
US05994291

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