HuagongsheHuagongshe Chemie-Druckbericht · Nur für Forschungszwecke
Perillaldehyde → Perilla alcohol
Beteiligte Stoffe
| Rolle | Name | HCID | Einwaage |
|---|---|---|---|
| Edukt | Perillaldehyde | HCID 16441 | — |
| Edukt | Selenium Dioxide | HCID 24007 | — |
| Edukt | (+)-Limonene | HCID 440917 | — |
| Katalysator | chromium (VI) trioxide | HCID 10219390 | — |
| Produkt | Perilla alcohol | HCID 369312 | — |
Reaktionsschritte
Perillyl alcohol can be produced by reacting limonene with selenium dioxide (that is toxic) and other oxidants (that are difficult to work with i.e., anhydrous chromium trioxide) to yield various oxidation products, including a small amount of perillaldehyde. Once isolated, perillaldehyde is reduced to afford perillyl alcohol. While this two-step process is conceptually attractive, the oxidation of limonene to give perillyl alcohol proceeds in a low overall yield.
Herkunft & Nachweise
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patentnummer | US05994598 |
| Quelldatensatz | uspto-grants-1999_11 |
| ORD ID | ord-efc8b7b2544149a1a9a6fdf90618994b |
| Quellennotiz | uspto-grants-1999_11 |