Oxygen → Hydroperoxide, phenylmethyl
Reaktionsgleichung
[O:1]=[O:2].[C:3]1([CH3:9])[CH:8]=[CH:7][CH:6]=[CH:5][CH:4]=1>>[CH2:9]([O:1][OH:2])[C:3]1[CH:8]=[CH:7][CH:6]=[CH:5][CH:4]=1Komponenten
3
Versuchsvorschrift
750 G of toluene are introduced into a 1.5 liter stainless steel autoclave which is shaken; the toluene is oxidised, at 180°C under a pressure of 20 bars, with air depleted of oxygen until it contains only 8%, with an hourly flow rate of 240 liters (measured under normal temperature and pressure). After 1 hour 30 minutes the reaction mixture is cooled. The hydroperoxide is then purified via its sodium salt. 11.4 G of benzyl hydroperoxide, containing 85% by weight of pure product, are thus obtained.
Aufarbeitung
- customis oxidised, at 180°C under a pressure of 20 bars, with air
- temperatureAfter 1 hour 30 minutes the reaction mixture is cooled
- customThe hydroperoxide is then purified via its sodium salt
- addition11.4 G of benzyl hydroperoxide, containing 85% by weight of pure product
- customare thus obtained
Quellen und Nachweise
- ORD-Eintrag
- ord-8d465e630e6645a18cda1fa38fb4bfbb
- Quelldatensatz
- uspto-grants-1976_04
- Patentnummer
- US03948995
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