HCID 21409396, Verbindung → 1-[4-(1-Hydroxy-2,2-dimethylpropyl)phenyl]propan-1-one
Reaktionsgleichung
CC1(C2C=CC(C(O)C(C)(C)C)=CC=2)OCCO1.CC1(C2C=CC(C(O)C(C)(C)C)=CC=2Cl)OCCO1.[CH2:38]([C:40]1([C:45]2[CH:50]=[CH:49][C:48]([CH:51]([OH:56])[C:52]([CH3:55])([CH3:54])[CH3:53])=[CH:47][CH:46]=2)OCC[O:41]1)[CH3:39]>>[C:40]([C:45]1[CH:50]=[CH:49][C:48]([CH:51]([OH:56])[C:52]([CH3:55])([CH3:54])[CH3:53])=[CH:47][CH:46]=1)(=[O:41])[CH2:38][CH3:39]Komponenten
4
Versuchsvorschrift
When the above reaction is carried out using in place of 2-methyl-2-(4-[1-hydroxy-2,2-dimethylpropyl]-phenyl)1,3-dioxolane, and equivalent amount of 2-methyl-2-(2-chloro-4-[1-hydroxy-2,2-dimethylpropyl]-phenyl)-1,3-dioxolane, or 2-ethyl-2 -(4-[1-hydroxy-2,2-dimethylpropyl]-phenyl)-1,3-dioxolane, there is obtained 1-(2-chloro-p-acetophenyl)-2,2-dimethylpropanol or 1-(p-propionylphenyl)-2,2-dimethylpropanol.