3,3-Dinitroazetidine → 3,3-Dinitroazetidinium 2,4-dinitroimidazolate

HRID 1608676Notizen

Reaktionsgleichung

Reaktionsgleichung von HRID 1608676
[N+:1]([C:4]1([N+:8]([O-:10])=[O:9])[CH2:7][NH:6][CH2:5]1)([O-:3])=[O:2].[N+:11]([C:14]1[NH:15][CH:16]=[C:17]([N+:19]([O-:21])=[O:20])[N:18]=1)([O-:13])=[O:12]>C(#N)C>[N+:11]([C:14]1[N-:15][CH:16]=[C:17]([N+:19]([O-:21])=[O:20])[N:18]=1)([O-:13])=[O:12].[N+:1]([C:4]1([N+:8]([O-:10])=[O:9])[CH2:7][NH2+:6][CH2:5]1)([O-:3])=[O:2]

Komponenten

4

Edukt 2

HCID 52317063,3-DinitroazetidineHCID 178526857HCID 178526857, Verbindung

Produkt 1

HCID 1317189183,3-Dinitroazetidinium 2,4-dinitroimidazolateAusbeute 95 %

Reagenzien, Katalysatoren, Lösungsmittel 1

HCID 6342AcetonitrileLösungsmittel

Versuchsvorschrift

3,3-Dinitroazetidine free base (1.0 g) was added to a solution of 2,4-dinitroimidazole (1.07 g) in 50 ml of warm acetonitrile. The solution was allowed to cool and the majority of the solvent evaporated. The remaining slurry was filtered and dried to give 1.98 g of the resultant product, 3,3-dinitroazetidinium 2,4-dinitroimidazolate (95% yield).

Aufarbeitung

  1. temperatureto cool
  2. customthe majority of the solvent evaporated
  3. filtrationThe remaining slurry was filtered
  4. customdried

Quellen und Nachweise

ORD-Eintrag
ord-f2cc1d08b8f14befacdfcb47b96c50ce
Quelldatensatz
uspto-grants-1995_03
Patentnummer
US05395945

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