Ethanol → Sodium 4-allyloxyphenylsulfonate

HRID 1608852

Reaktionsgleichung

Reaktionsgleichung von HRID 1608852
[C:1]1([S:7]([O-:10])(=[O:9])=[O:8])[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.[Na+:11].[CH2:12](Br)[CH:13]=[CH2:14].C([OH:18])C>[OH-].[Na+]>[CH2:12]([O:18][C:4]1[CH:5]=[CH:6][C:1]([S:7]([O-:10])(=[O:9])=[O:8])=[CH:2][CH:3]=1)[CH:13]=[CH2:14].[Na+:11]

Komponenten

5

Edukt 3

HCID 702EthanolHCID 7841Allyl bromideHCID 517327Sodium benzenesulfonate

Produkt 1

HCID 86748076Sodium 4-allyloxyphenylsulfonate

Reagenzien, Katalysatoren, Lösungsmittel 1

HCID 14798Sodium HydroxideLösungsmittel

Versuchsvorschrift

30 g of sodium phenylsulfonate are dissolved in 60 ml of ethanol and 50 ml of 15% sodium hydroxide, 20 g of allyl bromide are added and the mixture is refluxed for 48 hours. The ethanol is concentrated and the precipitate obtained is filtered off and then dried under vacuum in the presence of phosphorus pentoxide to give 23.3 g of the expected product.

Aufarbeitung

  1. temperaturethe mixture is refluxed for 48 hours
  2. concentrationThe ethanol is concentrated
  3. customthe precipitate obtained
  4. filtrationis filtered off
  5. dry with materialdried under vacuum in the presence of phosphorus pentoxide

Quellen und Nachweise

ORD-Eintrag
ord-b2935169068549b7b3b3c6441b652d28
Quelldatensatz
uspto-grants-1995_03
Patentnummer
US05397801

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